JKMRS Volume 19, No 1, pp 18-22; Structural characteristics of... | |
---|---|
2015년 06월 20일 / 조회수: 712 | |
Structural characteristics of [N(CH3)4]2CdCl4 determined
by 1H MAS NMR, 13C CP/ MAS NMR, and 14N NMR Seung
Jin Lee2 and Ae Ran Lim1, 2, * 1Department
of Science Education, Jeonju University, Jeonju 560-759, Korea 2Department
of Carbon Fusion Engineering, Jeonju University, Jeonju 560-759, Korea Received Mar 27, 2015; Revised
May 1, 2015; Accepted May 14, 2015 Abstract The structural geometry of [N(CH3)4]2CdCl4
in a hexagonal phase is studied by 1H MAS NMR, 13C CP/MAS
NMR, and 14N NMR. The changes in the chemical shifts for 13C
and 14N in the hexagonal phase are explained by the structural
geometry. In addition, the temperature dependencies of the spin-lattice
relaxation time in the rotating frame T1ρ for 1H MAS NMR
and 13C CP/MAS NMR are measured. Keywords [N(CH3)4]2CdCl4, Magic angle spinning, Static NMR, Nuclear magnetic resonance |
|
첨부파일 | 3이승진.pdf |